The process of slow π − absorption in 21 45 Sc, 27 59 Co, 39 89 Y, 55 133 Cs, 59 141 Pr and 79 197 Au atomic nuclei, followed by the emission of one proton, has been investigated. Upper limits for the probabilities of single-proton emission have been determined from the yields of the isotopes produced. The following values are obtained, per stopped pion: W ⩽ 6.1 × 10 −4 for the reaction 21 45 Sc(π − , p) 19 44 K, W ⩽ 0.87 × 10 −4 for 27 59 Co(π − , p) 25 58 Mn, W ⩽ 6.9 × 10 −4 for 39 89 Y(π − , p) 37 88 Rb, W ⩽ 1.3 × 10 −4 for 55 133 Cs(π − , p) 53 132 I, W ⩽ 3.0 × 10 −4 for 59 141 Pr(π − , p) 57 140 La, and W ⩽ 3.3 × 10 −5 for 79 197 Au(π − , p) 77 196m Ir.